Accepted in peer reviewed journals:
(74) X. Wang, F. Xiao, and F. W. Patureau*
CO2 and Palladium Enabled Highly Chemoselective Hydroxylation of gem-Difluorocyclopropanes
(73) V. Thönnißen, J. Westphäling, I. L. Atodiresei, and F. W. Patureau*
Atroposelective Chan-Evans-Lam Amination
(72) S. Nandi, A. Paffen, and F. W. Patureau*
Aromatic Amine Catalysts for the O2-mediated Cross Dehydrogenative Phenothiazination Reaction?
Synlett 2024, 35, 10.1055/a-2225-8736. (Cluster on Chemical Synthesis and Catalysis in Germany, edited by Prof. Benjamin List).
(71) V. Thönnißen, I. L. Atodiresei, and F. W. Patureau*
Atroposelective Nenitzescu Indole Synthesis
Chem. Eur. J. 2023, 29, e202300279.
Front Cover:
Chem. Eur. J. 2023, 29, e202300779.
Front Cover Profile:
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(70) D. Liu, Y. Zhao, and F. W. Patureau*
NaI/PPh3-catalyzed visible-light-mediated decarboxylative radical cascade cyclization of N-arylacrylamides for the efficient synthesis of quaternary oxindoles
Beilstein J. Org. Chem. 2023, 19, 57 (thematic issue guest edited by Prof. I. Chatterjee).
(69) X. Wang, and F. W. Patureau*
Pd-catalyzed access to mono- and di-fluoroallylic amines from primary anilines
(68) Y. Zhao, C. Empel, W. Liang, R. M. Koenigs* and F. W. Patureau*
Gem-Difluoroallylation of Aryl Sulfonium Salts
(67) R. Huang, and F. W. Patureau*
Electrochemical Dehydrogenative C−H Aminomethylation of Imidazopyridines and Related Heterocycles
Chem. Eur. J. 2022, 28, e202202135.
(66) D. A. Corbin, C. Cremer, K. O. Puffer, B. S. Newell, F. W. Patureau,* and G. M. Miyake*
Effects of the Chalcogenide Identity in N-Aryl Phenochalcogenazine Photoredox Catalysts
ChemCatChem 2022, 14, e202200485.
(65) J. Xiang, and F. W. Patureau*
Cross Dehydrogenative Coupling of Chloro- and Fluoroalkanes with Methylarenes
(64) C. Cremer, and F. W. Patureau*
O2-mediated Te(II)-redox catalysis for the cross dehydrogenative coupling of indoles
(63) R. Benchouaia, S. Nandi, C. Maurer, and F. W. Patureau*
O2-mediated dehydrogenative phenoxazination of phenols
(62) C. Yu, R. Huang, and F. W. Patureau*
Direct Dehydrogenative Access to Unsymmetrical Phenones
Angew. Chem. Int. Ed. 2022, 61, e202201142.
Highlighted by CBG资讯: (link).
Highlighted by ChemistryViews: (link).
(61) P. Y. Vemuri, C. Cremer, and F. W. Patureau*
Te(II)-catalyzed cross dehydrogenative phenothiazination of anilines
(60) Y. Zhao, C. Yu, W. Liang, I. L. Atodiresei, and F. W. Patureau*
TEMPO-mediated late stage photochemical hydroxylation of biaryl sulfonium salts
(59) X. Wang, C. Yu, I. L. Atodiresei, and F. W. Patureau*
Phosphine catalyzed dearomative [3+2] cycloaddition of benzoxazoles with a cyclopropenone
(58) R. Huang, C. Yu, and F. W. Patureau*
Electrochemical Dehydrogenative Acetalization Protection of Alcohols with Tetrahydrofuran
ChemElectroChem 2021, 8, 3943.
(57) HOT ARTICLE:
A. Tabey, P. Y. Vemuri and F. W. Patureau*
Cross Dehydrogenative N─N Couplings
(56) HOT ARTICLE:
C. Cremer, J. M. Merkes, C. L. Bub, D. Rommel, F. W. Patureau and S. Banala*
Leucomethylene blue probe detects a broad spectrum of reactive oxygen and nitrogen species
(55) Y. Zhao, C. Yu, W. Liang, and F. W. Patureau*
Photochemical (Hetero-)Arylation of Aryl Sulfonium Salts
Org. Lett. 2021, 23, 6232.
(54) P. Y. Vemuri, and F. W. Patureau*
Cross Dehydrogenative N─N Coupling of Aromatic and Aliphatic Methoxyamides with Benzotriazoles
Highlighted in Chem-Station: (link).
(53) C. Cremer, M. A. Eltester, H. Bourakhouadar, I. L. Atodiresei, and F. W. Patureau*
Dehydrogenative C─H Phenochalcogenazination
(52) C. Cremer, M. Goswami, C. K. Rank, B. de Bruin, and F. W. Patureau*
Tellurium(II)/Tellurium(III)-Catalyzed Cross-Dehydrogenative C─N Bond Formation
Angew. Chem. Int. Ed. 2021, 60, 6451.
Highlighted by CBG资讯: (link).
(51) C. Yu, B. Özkaya, and F. W. Patureau*
Electro-oxidative selective esterification of methylarenes and benzaldehydes
(50) V. Thönnißen, and F. W. Patureau*
Enantioselective aromatic amination?
(49) C. L. Bub, V. Thönnißen, and F. W. Patureau*
Benzophenothiazine and its Cr(III)-catalyzed cross dehydrogenative couplings
(48) B. Özkaya, C. L. Bub, and F. W. Patureau*
Step and redox efficient nitroarene to indole synthesis
(47) C. Yu, J. Sanjosé-Orduna, F. W. Patureau* and M. H. Pérez-Temprano*
Emerging unconventional organic solvents for C–H bond and related functionalization reactions
(46) P. Y. Vemuri, Y. Wang, F. W. Patureau*
Para-Selective Dehydrogenative Phenothiazination of Hydroquinolines and Indolines
Org. Lett. 2019, 21, 9856.
(45) C. Yu, F. W. Patureau*
Regioselective oxidative arylation of fluorophenols
Angew. Chem. Int. Ed. 2019, 58, 18530.
(44) C. K. Rank,§ A. W. Jones,§ T. Wall, P. Di Martino Fumo, S. Schröck, M. Gerhards, F. W. Patureau*
An intermolecular C―H oxidizing strategy to access highly fused carbazole skeletons from simple naphthylamines
Chem. Commun. 2019, 55, 13749. (§these two authors contributed equally).
(43) C. K. Rank, B. Özkaya, F. W. Patureau*
HBF4 and AgBF4 catalyzed ortho-alkylation of diarylamines and phenols
Org. Lett. 2019, 21, 6830.
(42) C. Empel, F. W. Patureau,* R. M. Koenigs*
Visible Light Induced Metal-Free Carbene N-Carbazolation
J. Org. Chem. 2019, 84, 11316.
(41) P. Weber, C. K. Rank, E. Yalcinkaya, M. Dyga, T. van Lingen, R. Schmid, F. W. Patureau,* L. J. Gooßen*
Rhodium-catalyzed ortho-Arylation of (Hetero)aromatic Acids
Adv. Synth. Catal. 2019, 361, 3925.
(40) F. W. Patureau
The Phenol-Phenothiazine Coupling: an Oxidative Click Concept
ChemCatChem 2019, 11, 5227.
(Concept Paper, special issue: New Concepts in Homogeneous Catalysis, guest edited by L. Ackermann and J.-B. Sortais).
(39) C. Yu, F. W. Patureau*
Cu-catalyzed cross-dehydrogenative ortho-aminomethylation of phenols
Angew. Chem. Int. Ed. 2018, 57, 11807.
(38) A. W. Jones, C. K. Rank, Y. Becker, C. Malchau, I. Funes-Ardoiz, F. Maseras,* F. W. Patureau*
Accelerated Ru-Cu trinuclear cooperative C-H bond functionalization of carbazoles: a kinetic and computational investigation
Chem. Eur. J. 2018, 24, 15178.
(37) F. W. Patureau, J. Groß, J. M. Ernsting, C. van Wüllen,* J. N. H. Reek*
P-N bridged dinuclear Rh-METAMORPhos complexes: NMR and computational studies
Eur. J. Inorg. Chem. 2018, 3761
(36) HOT PAPER:
M. Goswami, A. Konkel, M. Rahimi, M.-L. Louillat-Habermeyer, H. Kelm, R. Jin, B. de Bruin,* F. W. Patureau*
Mechanism of the dehydrogenative phenothiazination of phenols
Chem. Eur. J. 2018, 24, 11936.
(35) R. Jin,§ C. L. Bub,§ F. W. Patureau*
Phenothiazinimides: atom-efficient electrophilic amination reagents
Org. Lett. 2018, 20, 2884. (§these two authors contributed equally).
(34) C. K. Rank, T. Wall, F. Dietrich, M. Vidovic, M. P. Klein, Y. Sun, G. Niedner-Schatteburg,* M. Gerhards,* F. W. Patureau*
A phosphino-carboxylic acid based Ru dimeric complex
Eur. J. Inorg. Chem. 2018, 1394
(33) A. Bernhardt, H. Kelm, F. W. Patureau,*
The strong Beta-CF3 shielding effect in HFIP and 100 other organic solvents revisited with 17O NMR
ChemCatChem 2018, 10, 1547
(32) A. Malekafzali, K. Malinovska, F. W. Patureau,*
The cumene/O2 system: a very simple tool for the radical chain oxidation of some functional groups
N. J. Chem. 2017, 41, 6981. Why don't you just boil it in cumene!
(31) C. Heitz, A. W. Jones,§ B. S. Oezkaya,§ C. L. Bub,§ M.-L. Louillat-Habermeyer, V. Wagner, F. W. Patureau,*
Ru catalyzed dehydrogenative C-O bond formation with anilines and phenols
Chem. Eur. J. 2016, 22, 17980. (§these three authors contributed equally)
(30) R. Jin, F. W. Patureau,*
Mild, periodate mediated, dehydrogenative C-N bond formation with phenothiazines and phenols,
Org. Lett. 2016, 18, 4491.
Highlighted in SYNFACTS: Synfacts 2016, 12, 1246.
(29) J. Wencel-Delord,* F. W. Patureau, F. Glorius,
Rh(III) and Ir(III) catalyzed C-C bond cross couplings from C-H bonds,
Top. Organomet. Chem. 2016, 55, 1-27.
(28) A. W. Jones, M.-L. Louillat-Habermeyer & F. W. Patureau,*
Strained dehydrogenative ring closure of phenyl-carbazoles
Adv. Synth. Catal. 2015, 357, 945.
(27) M.-L. Louillat-Habermeyer, R. Jin & F. W. Patureau,*
O2-mediated dehydrogenative amination of phenols
Angew. Chem. Int. Ed. 2015, 54, 4102.
(26) R. Jin & F. W. Patureau,*
Invited: Highlight: Metal-free dehydrogenative isoquinolone synthesis,
ChemCatChem 2015, 7, 223.
(25) A. Biafora & F. W. Patureau,*
Invited: Perspective on Ru-Cu mediated dehydrogenative C-N bond Formation,
SYNPACTS article, Synlett 2014, 25, 2525.
(24) F. W. Patureau & L. J. Gooßen,
Invited: Book Review of "Copper Mediated Cross-Coupling Reactions", Editors: G. Evano & N. Blanchard, John Wiley & Sons 2013, ISBN 978-1118060452,
Angew. Chem. Int. Ed. 2014, 53, 5738.
(23) M.-L. Louillat, A. Biafora, F. Legros & F. W. Patureau,*
Ruthenium-Catalyzed Cross-Dehydrogenative ortho-N-Carbazolation of Diarylamines: Versatile Access to Unsymmetrical Diamines
Angew. Chem. Int. Ed. 2014, 53, 3505.
(22) M.-L. Louillat & F. W. Patureau,*
Oxidative C-H amination reactions,
Chem. Soc. Rev. 2014, 43, 901.
(21) S. Oldenhof, B. de Bruin, M. Lutz, M. A. Siegler, F. W. Patureau, J. I. van der Vlugt, J. N. H. Reek,
Base-free production of H2 by dehydrogenation of formic acid using an Iridium-bis-Metamorphos complex,
Chem. Eur. J. 2013, 19, 11507.
(20) M.-L. Louillat, F. W. Patureau,*
Towards polynuclear Ru-Cu catalytic dehydrogenative C-N bond formation, on the reactivity of carbazoles,
Org. Lett. 2013, 15, 164.
(19) F. W. Patureau, T. Besset, F. Glorius, checked by T. Harada, T. Fukuyama
Preperation of (E)-N,N-Diethyl-2-styrylbenzamide by Rh-catalyzed C-H activation
Org. Synth. 2013, 90, 41.
2012-2007
(18) F. W. Patureau,* T. Besset, R. Fröhlich, F. Glorius,*
On the selectivity in some Rh(III) catalyzed C-H activation cross-couplings, De la sélectivité dans des réactions d'hétéro-couplage par C-H activation catalysées au Rh(III).
C. R. Chim. 2012, 15, 1081.
(17) F. W. Patureau,* J. Wencel-Delord, F. Glorius*
Cp*Rh-catalyzed C-H activations: versatile dehydrogenative cross-couplings of Csp2 C-H positions with olefins, alkynes, and arenes
Aldrichimica Acta 2012, 45, 31.
(16) F. W. Patureau,
Atom tunneling in organic transformations,
Angew. Chem. Int. Ed. 2012, 51, 4784.
(15) J. Wencel-Delord, C. Nimphius, F. W. Patureau, F. Glorius,
[Rh(III)Cp*]-Catalyzed Dehydrogenative Alkene–Arene Coupling as a New Pathway for the Selective Synthesis of Highly Substituted Z Olefins,
Chem. Asian J. 2012, 7, 1208.
(14) J. Wencel-Delord, C. Nimphius, F. W. Patureau, F. Glorius,
[Rh(III)Cp*]-Catalyzed Dehydrogenative Aryl-Aryl Bond Formation,
Angew. Chem. Int. Ed. 2012, 51, 2247. HOT PAPER.
(13) F. W. Patureau, C. Worch, M. A. Siegler, A. L. Spek, C. Bolm, J. N. H. Reek,
SIAPhos: Phosphorylated Sulfonimidamides and their Use in Iridium-Catalyzed Asymmetric Hydrogenations of Sterically Hindered Cyclic Enamides,
Adv. Synth. Catal. 2012, 354, 59.
(12) F. W. Patureau, M. A. Siegler, A. L. Spek, A. J. Sandee, S. Jugé, S. Aziz, A. Berkessel, J. N. H. Reek,
Supramolecular H-bonding Tautomeric Sulfonamido-Phosphinamides: a Perfect P-Chirogenic Memory,
Eur. J. Inorg. Chem. 2012, 496.
(11) F. W. Patureau, C. Nimphius, F. Glorius,
Rh Catalyzed C–H Activation and Oxidative Olefination without Chelate Assistance: On the Reactivity of Bromoarenes,
Org. Lett. 2011, 13, 6346.
(10) T. Besset, N. Kuhl, F. W. Patureau, F. Glorius,
Rh(III)-Catalyzed Oxidative Olefination of Vinylic C-H Bonds: Efficient and Selective Access to Di-unsaturated α-Amino Acid Derivatives and other Linear 1,3-Butadienes,
Chem. Eur. J. 2011, 17, 7167.
(9) F. W. Patureau, T. Besset, N. Kuhl, F. Glorius,
Diverse strategies towards indenol and fulvene derivatives: Rh-catalyzed C-H activation of aryl ketones followed by coupling with internal alkynes,
J. Am. Chem. Soc. 2011, 133, 2154.
(8) F. W. Patureau* and F. Glorius*
Oxidizing directing groups enabling efficient and innovative C-H activation reactions,
Angew. Chem. Int. Ed. 2011, 50, 1977.
(7) F. W. Patureau, T. Besset, F. Glorius,
Rh Catalyzed Oxidative Olefination of C-H Bonds in Acetophenones and Benzamides,
Angew. Chem. Int. Ed. 2011, 50, 1064.
(6) F. W. Patureau, F. Glorius,
Rh Catalyzed Olefination and Vinylation of Unactivated Acetanilides,
J. Am. Chem. Soc. 2010, 132, 9982.
(5) S. Rakshit, F. W. Patureau, F. Glorius,
Pyrrole Synthesis via Allylic sp3 C-H Activation of Enamines Followed by Intermolecular Coupling with Unactivated Alkynes,
J. Am. Chem. Soc. 2010, 132, 9585.
(4) F. W. Patureau, S. de Boer, M. Kuil, J. Meeuwissen, P.-A. R. Breuil, M. A. Siegler, A. L. Spek, A. J. Sandee, B. de Bruin, J. N. H. Reek,
Sulfonamido-Phosphoramidite Ligands in Cooperative Dinuclear Hydrogenation Catalysis,
J. Am. Chem. Soc. 2009, 131, 6683.
(3) P.-A. R. Breuil, F. W. Patureau, J. N. H. Reek,
Singly Hydrogen Bonded Supramolecular Ligands for highly Selective Rhodium-Catalyzed Hydrogenation Reactions,
Angew. Chem. Int. Ed. 2009, 48, 2162.
(2) F. W. Patureau, M. Kuil, A. J. Sandee, J. N. H. Reek,
METAMORPhos: Adaptive Supramolecular Ligands and their Mechanistic Consequences for Asymmetric Hydrogenation,
Angew. Chem. Int. Ed. 2008, 47, 3180.
(1) M. Mellah, B. Ansel, F. Patureau, A. Voituriez, E. Schulz,
Electropolymerized Chromium-salen Complexes for the Heterogeneous Asymmetric Hetero-Diels-Alder Reaction,
J. Mol. Cat. A: Chem. 2007, 272, 1-2, 20.
Patents
(a) Reek, J. N. H.; Patureau, F. W.; Kuil, M.; Sandee, A. J.; Eur. Pat. Appl. 2009, EP 2062906 A1 20090527.
(b) Reek, J. N. H.; Patureau, F. W.; Kuil, M.; Sandee, A. J.; Meeuwissen, J.; PCT Int. Appl. 2009, WO 2009065856 A1 20090528.